Synthesis, structure and thermal contraction of a new low-temperature polymorph of ZrMo2O8

被引：33

作者：

Allen, S ^{[1
]}

Warmingham, NR ^{[1
]}

Gover, RKB ^{[1
]}

Evans, JSO ^{[1
]}

机构：

[1] Univ Durham, Dept Chem, Sci Labs, Durham DH1 3LE, England

来源：

CHEMISTRY OF MATERIALS | 2003年 / 15卷 / 18期

关键词：

D O I：

10.1021/cm034397s

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We report the synthesis and characterization of a new negative thermal expansion polymorph of zirconium molybdate, LT-ZrMo2O8, and suggest a possible topotactic mechanism for its formation from a precursor phase. The successful identification of this phase sheds new light on the pathway by which cubic ZrMo2O8 can be synthesized and allows one to quantify this process using in situ diffraction experiments for the first time.

引用

页码：3406 / 3410

页数：5

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