Preparation and characterization of Ti/Diamond electrodes

被引：51

作者：

Fisher, V

Gandini, D

Laufer, S

Blank, E

Comninellis, C ^{[1
]}

机构：

[1] Swiss Fed Inst Technol, Inst Chem Engn, CH-1015 Lausanne, Switzerland

[2] Swiss Fed Inst Technol, Dept Mat, Met Phys Lab, CH-1015 Lausanne, Switzerland

来源：

ELECTROCHIMICA ACTA | 1998年 / 44卷 / 2-3期

关键词：

D O I：

10.1016/S0013-4686(98)00116-9

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Boron doped diamond films have been deposited on Ti substrates by CVD. Raman spectroscopy reveals the presence of small amounts of nondiamond carbon. According to SEM;ind XRD, the diamond Rims polycrystalline with preferential [112] crystallite orientation. Electrochemical measurements show that Fe(CN)(6)(3-/4-) couple behaves in a quasi-reversible manner at the Ti/Diamond electrode. The main reason of the successful preparation of the Ti/Diamond electrode is the formation of an conductive TIC interlayer between the Ti substrate and the diamond coating. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.

引用

页码：521 / 524

页数：4

共 14 条

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