Synthesis and properties of dendritic polymers based on natural amino acids

被引:11
作者
Bilibin, A [1 ]
Zorin, I [1 ]
Saratovsky, S [1 ]
Moukhina, I [1 ]
Egorova, G [1 ]
Girbasova, N [1 ]
机构
[1] St Petersburg State Univ, Inst Chem, St Petersburg 198504, Russia
关键词
alpha-amino acids; dendritic polymers; solubility; synthesis; viscosity;
D O I
10.1002/masy.200350917
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Different approaches, including polycondensation, polymerization, polymer analog condensation, and ionic binding have been investigated for synthesis of amino acid-based dendritic polymers. It was shown that a growth of dendrons generation prevents obtaining of products with high polymerization degree in polycondensation and polymerization procedures. In polymer analog condensation a growth of dendrons generation leads to considerable decrease of polymer analog reaction rate as well as substitution degree. Degree of ionic binding depends on a strength of ionogenic groups and dendrns generation.
引用
收藏
页码:197 / 208
页数:12
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