Synthesis of quaternary amino acids containing beta,gamma- as well as gamma,delta-unsaturated side chains via chelate-enolate Claisen rearrangement

被引：17

作者：

Kazmaier, U

机构：

[1] Organisch Chemisches Institut, Universität Heidelberg, D-69120 Heidelberg

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 30期

关键词：

D O I：

10.1016/0040-4039(96)01104-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Ester enolate Claisen rearrangement of chelated N-protected alpha,beta-unsaturated amino acid allylic esters results in a migration of the double bond and the formation of highly unsaturated amino acids in good yields and in a highly diastereoselective fashion. Copyright (C) 1996 Elsevier Science Ltd

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页码：5351 / 5354

页数：4

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