Reduction of nitro-aryl compounds with zinc in the presence of poly[N-(2-aminoethyl)acrylamido]-trimethylammonium chloride as a phase-transfer catalyst

被引：23

作者：

Mahdavi, H

Tamami, B

机构：

[1] Univ Tehran, Fac Sci, Dept Chem, Tehran, Iran

[2] Shiraz Univ, Dept Chem, Shiraz, Iran

来源：

SYNTHETIC COMMUNICATIONS | 2005年 / 35卷 / 08期

关键词：

phase transfer catalyst; nitro reduction; zinc; polyacrylamide;

D O I：

10.1081/SCC-200054221

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The new polymeric phase-transfer catalyst, poly [N-(2-aminoethyl)acrylamido]trimethylammonium chloride resin, catalyzes the reduction of nitroarenes to the corresponding aromatic amines with zinc powder in water and in high yields under mild conditions.

引用

收藏

页码：1121 / 1127

页数：7

相关论文

共 30 条

[1] SELECTIVE REDUCTION OF NITROARYLALKYLNITRILES WITH HYDRAZINE AND A METAL CATALYST [J].

ADGER, BM ;

YOUNG, RG .

TETRAHEDRON LETTERS, 1984, 25 (45) :5219-5222

[2]

Anastas PT, 1998, GREEN CHEMISTRY, P1

[3]

[Anonymous], 1943, ORGANIC SYNTH

[4] Chemoselective reduction of nitroaromatics to anilines using decaborane in methanol [J].

Bae, JW ;

Cho, YJ ;

Lee, SH ;

Yoon, CM .

TETRAHEDRON LETTERS, 2000, 41 (02) :175-177

[5] A facile reduction of aromatic nitro compounds to aromatic amines by samarium and iodine [J].

Banik, BK ;

Mukhopadhyay, C ;

Venkatraman, MS ;

Becker, FF .

TETRAHEDRON LETTERS, 1998, 39 (40) :7243-7246

[6] ELECTRONIC SPECTRA OF ORGANIC MOLECULES AND THEIR INTERPRETATION .5. EFFECT OF TERMINAL GROUPS CONTAINING MULTIPLE BONDS ON THE K-BANDS OF CONJUGATED SYSTEMS [J].

BURAWOY, A ;

CRITCHLEY, JP .

TETRAHEDRON, 1959, 5 (04) :340-351

[7]

C-J Li, 1997, ORGANIC REACTIONS AQ, P1

[8]

Cho YS, 2003, B KOREAN CHEM SOC, V24, P653

[9] HOST GUEST COMPLEXATION .42. PREORGANIZATION STRONGLY ENHANCES THE TENDENCY OF HEMISPHERANDS TO FORM HEMISPHERAPLEXES [J].

DOXSEE, KM ;

FEIGEL, M ;

STEWART, KD ;

CANARY, JW ;

KNOBLER, CB ;

CRAM, DJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (10) :3098-3107

[10] SELECTIVE REDUCTION OF NITRO-COMPOUNDS WITH TITANIUM(II) REAGENTS [J].

GEORGE, J ;

CHANDRASEKARAN, S .

SYNTHETIC COMMUNICATIONS, 1983, 13 (06) :495-499