Bromo(N,N-dibutyl-N'-phenylthiourea-S)bis(triphenylphosphine-P)copper(I), [Cu(PPh(3))(2)(dbptH)Br]

被引：5

作者：

Singh, R ^{[1
]}

Dikshit, SK ^{[1
]}

机构：

[1] INDIAN INST TECHNOL,DEPT CHEM,KANPUR 208016,UTTAR PRADESH,INDIA

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270195006500

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The coordination around the Cu-metal centre in the title compound, [CUBr(C15H24N2S)(C18H15P)(2)], is distorted tetrahedral with bond lengths Cu-S 2.367(1), Cu-Br 2.469(1), Cu-P(1) 2.279(2) and Cu-P(2) 2.284(2) Angstrom, and bond angles S-Cu-Br 111.86(5), S-Cu-P(1) 111.28(6), S-Cu-P(2) 98.01(6), Br-Cu-P(1) 103.08(5), Br-Cu-P(2) 108.60(5) and P(1)-Cu-P(2) 124.11(6)degrees. The H atom of the NH group is intramolecularly hydrogen bonded to the Br atom, with an NH ... Br distance of 2.411 Angstrom.

引用

页码：635 / 637

页数：3

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