Liquid densities and excess molar volumes for water plus diethylene glycolamine, and water, methanol, ethanol, 1-propanol + triethylene glycol binary systems at atmospheric pressure and temperatures in the range of 283.15-363.15 K

被引:82
作者
Valtz, A
Teodorescu, M
Wichterle, I
Richon, D
机构
[1] Ecole Natl Super Mines, Ctr Energet, CENERG,TEP, Lab Thermodynam & Equilibres Entre Phases, F-77305 Fontainebleau, France
[2] Acad Sci Czech Republ, Inst Chem Proc Fundamentals, CR-16502 Prague, Czech Republic
关键词
diethylene glycolamine; triethylene glycol; water; methanol; ethanol; 1-propanol; density; experimental; excess molar volume;
D O I
10.1016/S0378-3812(03)00364-9
中图分类号
O414.1 [热力学];
学科分类号
摘要
Liquid densities and excess molar volumes (V-E) are reported for the binary water + diethylene glycolamine, and water, methanol, ethanol, I-propanol + triethylene glycol systems at atmospheric pressure and temperatures between 283.15 and 363.15 K in 10 K intervals. Negative V-E were found for all investigated systems. At given temperature, the most negative V-E is for the water + diethylene glycolamine system. For water containing systems, V-E increase with temperature while the inverse effect was observed for alcoholic systems, i.e. V-E became more negative with increasing temperature. For the triethylene glycol systems at constant temperature, absolute value of V-E decreases in the series: water > methanol > ethanol > 1-propanol within the whole composition range. The experimental results have been correlated using the three parameter Redlich-Kister equation. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:129 / 142
页数:14
相关论文
共 25 条
[1]   Volumetric properties of aqueous solutions of ethylene glycol oligomers at 25 degrees C [J].
Ambrosone, L ;
Sartorio, R ;
Vescio, A ;
Vitagliano, V .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1996, 92 (07) :1163-1166
[2]  
BETTIN H, 1990, PTB-MITT, V100, P195
[3]   MICROWAVE-SPECTRUM, DIPOLE-MOMENT, AND INTRAMOLECULAR HYDROGEN-BOND OF 2-METHOXYETHANOL [J].
BUCKLEY, P ;
BROCHU, M .
CANADIAN JOURNAL OF CHEMISTRY, 1972, 50 (08) :1149-&
[4]   DENSITIES AND REFRACTIVE INDICES FOR GLYCOL-WATER SOLUTIONS - TRIETHYLENE GLYCOL, DIPROPYLENE GLYCOL, AND HEXYLENE GLYCOL [J].
CHIAO, TT ;
THOMPSON, AR .
ANALYTICAL CHEMISTRY, 1957, 29 (11) :1678-1681
[5]   Isothermal vapour-liquid equilibria and excess molar volumes in the binary ethanol plus methyl propanoate or methyl butanoate systems [J].
Constantinescu, D ;
Wichterle, I .
FLUID PHASE EQUILIBRIA, 2002, 203 (1-2) :71-82
[6]   DENSITIES AND DERIVED VOLUME FUNCTIONS OF BINARY-MIXTURES - (AN ETHYLENE-GLYCOL DERIVATIVE + WATER) AT 298.15-K [J].
DETHLEFSEN, C ;
HVIDT, AASE .
JOURNAL OF CHEMICAL THERMODYNAMICS, 1985, 17 (02) :193-199
[7]   DENSITIES AND VISCOSITIES OF THE BINARY-MIXTURES OF INTEREST FOR ABSORPTION-REFRIGERATION SYSTEMS AND HEAT-PUMPS [J].
ESTEVE, X ;
OLIVE, F ;
PATIL, KR ;
CHAUDHARI, SK ;
CORONAS, A .
FLUID PHASE EQUILIBRIA, 1995, 110 (1-2) :369-382
[8]  
FISCHER K, 1999, INT ELECT PHYS CHEM, V5, P97
[9]   Volumetric properties and viscosities for aqueous diglycolamine solutions from 25 °C to 70 °C [J].
Henni, A ;
Tontiwachwuthikul, P ;
Chakma, A ;
Mather, AE .
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2001, 46 (01) :56-62
[10]   DENSITIES, VISCOSITIES AND AMINE DIFFUSIVITIES OF AQUEOUS MIPA, DIPA, DGA AND EDA SOLUTIONS [J].
HIKITA, H ;
ISHIKAWA, H ;
MURAKAMI, T ;
ISHII, T .
JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1981, 14 (05) :411-413