A TEMPO-substituted polyacrylamide as a new cathode material: an organic rechargeable device composed of polymer electrodes and aqueous electrolyte

被引：140

作者：

Koshika, Kenichiroh ^{[1
]}

Chikushi, Natsuru ^{[1
]}

Sano, Naoki ^{[1
]}

Oyaizu, Kenichi ^{[1
]}

Nishide, Hiroyuki ^{[1
]}

机构：

[1] Waseda Univ, Dept Appl Chem, Tokyo 1698555, Japan

来源：

GREEN CHEMISTRY | 2010年 / 12卷 / 09期

关键词：

RADICAL POLYMERS; BATTERIES; SUPERCAPACITOR; HYDROGELS; SAFETY;

D O I：

10.1039/b926296b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Poly(2,2,6,6-tetramethylpiperidinyloxy-4-yl acrylamide) was designed and synthesized as an electrode-active polymer for an organic rechargeable device containing an aqueous electrolyte. The device demonstrated a 1.2 V output voltage, exceeded 2000 charging-discharging cycles, and had a high charging rate performance within 1 min.

引用

页码：1573 / 1575

页数：3

共 21 条

[1]

Anastas P. T., GREEN CHEM THEORY PR

[2] Safety mechanisms in lithium-ion batteries [J].

Balakrishnan, PG ;

Ramesh, R ;

Kumar, TP .

JOURNAL OF POWER SOURCES, 2006, 155 (02) :401-414

[3] Polyaniline-deposited porous carbon electrode for supercapacitor [J].

Chen, WC ;

Wen, TC ;

Teng, HS .

ELECTROCHIMICA ACTA, 2003, 48 (06) :641-649

[4] Pseudopolyrotaxanes made to order: Cucurbituril threaded on polyviologen [J].

Choi, S ;

Lee, JW ;

Ko, YH ;

Kim, K .

MACROMOLECULES, 2002, 35 (09) :3526-3531

[5] Solid-state, polymer-based, redox capacitors [J].

Clemente, A ;

Panero, S ;

Spila, E ;

Scrosati, B .

SOLID STATE IONICS, 1996, 85 (1-4) :273-277

[6] Chemistry, biochemistry, and safety of acrylamide. A review [J].

Friedman, M .

JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2003, 51 (16) :4504-4526

[7] Mechanism of forming organic/inorganic network structures during in-situ free-radical polymerization in PNIPA-clay nanocomposite hydrogels [J].

Haraguchi, K ;

Li, HJ ;

Matsuda, K ;

Takehisa, T ;

Elliott, E .

MACROMOLECULES, 2005, 38 (08) :3482-3490

[8] A rechargeable battery based on hydrophilic radical polymer electrode and its green assessment [J].

Koshika, K. ;

Kitajima, M. ;

Oyaizu, K. ;

Nishide, H. .

GREEN CHEMISTRY LETTERS AND REVIEWS, 2009, 2 (03) :169-174

[9] An ultrafast chargeable polymer electrode based on the combination of nitroxide radical and aqueous electrolyte [J].

Koshika, Kenichiroh ;

Sano, Naoki ;

Oyaizu, Kenichi ;

Nishide, Hiroyuki .

CHEMICAL COMMUNICATIONS, 2009, (07) :836-838

[10] An Aqueous, Electrolyte-Type, Rechargeable Device Utilizing a Hydrophilic Radical Polymer-Cathode [J].

Koshika, Kenichiroh ;

Sano, Naoki ;

Oyaizu, Kenichi ;

Nishide, Hiroyuki .

MACROMOLECULAR CHEMISTRY AND PHYSICS, 2009, 210 (22) :1989-1995

← 1 2 3 →