Lattice constants and molar volume in the system ZnS, ZnSe, CdS, CdSe

被引：72

作者：

Hotje, U ^{[1
]}

Rose, C ^{[1
]}

Binnewies, M ^{[1
]}

机构：

[1] Univ Hannover, Inst Anorgan Chem, D-30167 Hannover, Germany

来源：

SOLID STATE SCIENCES | 2003年 / 5卷 / 09期

关键词：

mixed crystals ZnxCd1-xSySe1-y; lattice constants; Vegard's law;

D O I：

10.1016/S1293-2558(03)00177-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In the system ZnS/ZnSe/CdS/CdSe mixed crystals have been prepared in presence of iodine vapor as a mineralisator gas. Crystallographic parameters of the mixed crystals have been determined by X-ray powder methods. Mixed crystals with high Zn content crystallize in the sphalerite-structure, other ones in the wurtzite-structure. Molar volumes derived from experimentally determined lattice constants can be given in form of a plane as a function of the composition of the mixed phases. Vegard's law is often discussed in binary systems as a straight line. The corresponding plane for the system ZnS/ZnSe/CdS/CdSe is presented here. (C) 2003 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

引用

页码：1259 / 1262

页数：4