Concerted Diels-Alder reaction between anthracene and C60

被引：18

作者：

Chronakis, N ^{[1
]}

Orfanopoulos, M ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 71409, Crete, Greece

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 06期

关键词：

fullerenes; 4+2] cycloaddition; isotope effects; hyperconjugation;

D O I：

10.1016/S0040-4039(00)02211-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The Diels-Alder reaction of anthracene with C-60 has been investigated experimentally by using secondary isotope effects. The inverse alpha -secondary isotope effect in conjunction with the unity value of the P-secondary isotope effect indicates a concerted mechanism for the title reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1201 / 1204

页数：4

共 14 条

[1]

DIEDERICH F, 1994, CHEM SOC REV, P243

[2] SYNTHESES OF 9,10-DISUBSTITUTED ANTHRACENES DERIVED FROM 9,10-DILITHIOANTHRACENE [J].