Trapping of n-butyllithium dimer by a trilithiated derivative of {Al[N(H)But]3}2

被引：31

作者：

Brask, JK

Chivers, T

Yap, GPA

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 22期

关键词：

D O I：

10.1039/a807081d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of {Al[N(H)Bu-t](3)}(2), obtained as a 1 : 2 mixture of cis and trans isomers from the addition of AlCl3 to three equiv. LiN(H)Bu-t in diethyl ether, with LiBun generates a complex in which a dimeric n-butyllithium fragment is trapped by the trilithiated derivative Li3Al2[N(H)Bu-t](3)[N-Bu-t](3).

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收藏

页码：2543 / 2544

页数：2

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