Fluorescence methods in the study of the interactions of surfactants with polymers

被引:327
作者
Winnik, FM
Regismond, STA
机构
[1] Dept. of Chem./Physics and Astronomy, McMaster University, Hamilton, Ont. L8S 4MI
基金
加拿大自然科学与工程研究理事会;
关键词
aggregation number; critical aggregation concentration; fluorescence; fluorescence probe; hydrophobically-modified polymers; micelle; polyelectrolyte; polymer-surfactant interaction; proteins;
D O I
10.1016/0927-7757(96)03733-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this review we present the application of fluorescence techniques to study polymer-surfactant systems, discussing the various methods and materials in use. In the first section we consider the use of low molecular weight fluorescence probes to measure the critical aggregation concentration and aggregation number of polymer-surfactant complexes and to characterize the microenvironment within the complexes. The next section deals exclusively with the association of fluorescently-labeled polymers and surfactants. The final part of the review is dedicated to a description of selected recent investigations, with particular emphasis on the study of the complexes formed between surfactants and hydrophobically-modified polymers.
引用
收藏
页码:1 / 39
页数:39
相关论文
共 168 条
[1]   EXPLORATORY-STUDY OF THE EFFECT OF POLY-ELECTROLYTE SURFACTANT AGGREGATES ON PHOTOCHEMICAL BEHAVIOR [J].
ABUIN, EB ;
SCAIANO, JC .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (21) :6274-6283
[2]   FLUORESCENCE DECAY KINETICS IN MONODISPERSE CONFINEMENTS WITH EXCHANGE OF PROBES AND QUENCHERS [J].
ALMGREN, M ;
LOFROTH, JE ;
VANSTAM, J .
JOURNAL OF PHYSICAL CHEMISTRY, 1986, 90 (18) :4431-4437
[3]   AGGREGATION OF ALKYLTRIMETHYLAMMONIUM SURFACTANTS IN AQUEOUS POLY(STYRENESULFONATE) SOLUTIONS [J].
ALMGREN, M ;
HANSSON, P ;
MUKHTAR, E ;
VANSTAM, J .
LANGMUIR, 1992, 8 (10) :2405-2412
[4]   AGGREGATION OF POLY(ETHYLENE OXIDE)-POLY(PROPYLENE OXIDE)-POLY(ETHYLENE OXIDE) TRIBLOCK COPOLYMERS IN THE PRESENCE OF SODIUM DODECYL-SULFATE IN AQUEOUS-SOLUTION [J].
ALMGREN, M ;
VANSTAM, J ;
LINDBLAD, C ;
LI, PY ;
STILBS, P ;
BAHADUR, P .
JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (14) :5677-5684
[5]   COMPARTMENTAL MODELING OF EXCITED-STATE REACTIONS - IDENTIFIABILITY OF THE RATE CONSTANTS FROM FLUORESCENCE DECAY SURFACES [J].
AMELOOT, M ;
BEECHEM, JM ;
BRAND, L .
CHEMICAL PHYSICS LETTERS, 1986, 129 (03) :211-219
[6]  
[Anonymous], DISCUSS FARADAY SOC
[7]   Interactions between water-soluble polymers and surfactants: Effect of the polymer hydrophobicity .1. Hydrophilic polyelectrolytes [J].
Anthony, O ;
Zana, R .
LANGMUIR, 1996, 12 (08) :1967-1975
[8]   EFFECT OF TEMPERATURE ON THE INTERACTIONS BETWEEN NEUTRAL POLYMERS AND A CATIONIC AND A NONIONIC SURFACTANT IN AQUEOUS-SOLUTIONS [J].
ANTHONY, O ;
ZANA, R .
LANGMUIR, 1994, 10 (11) :4048-4052
[9]   PROBE METHODS FOR THE 2ND CMC OF FLUOROCARBON AND HYDROCARBON SURFACTANT MIXTURES [J].
ASAKAWA, T ;
MOURI, M ;
MIYAGISHI, S ;
NISHIDA, M .
LANGMUIR, 1989, 5 (02) :343-348
[10]   FLUORESCENCE STUDIES OF DANSYL-LABELED POLY(N-ISOPROPYLACRYLAMIDE) GELS AND POLYMERS IN MIXED WATER/METHANOL SOLUTIONS [J].
ASANO, M ;
WINNIK, FM ;
YAMASHITA, T ;
HORIE, K .
MACROMOLECULES, 1995, 28 (17) :5861-5866