Chemiluminescence from tetramethyldioxetane in poly(methyl methacrylate) and polystyrene

被引：4

作者：

Broska, R

Rychly, J

MatisovaRychla, L

机构：

[1] Polymer Institute, Slovak Academy of Sciences, 842 36 Bratislava

来源：

EUROPEAN POLYMER JOURNAL | 1996年 / 32卷 / 11期

关键词：

D O I：

10.1016/S0014-3057(96)00099-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The kinetics of chemiluminescence accompanying the thermal decomposition of tetramethyl-1,2-dioxetane (TMD) in a polymethyl methacrylate matrix and a polystyrene matrix has been investigated at isothermal and non-isothermal conditions. Induced decomposition of TMD by excited activator-9,10-dibromoanthracene (DBA)-has been observed for a PMMA matrix and the energy transfer radius for this process has been estimated. The different values of activation parameters obtained by both methods are discussed. Copyright (C) 1996 Elsevier Science Ltd

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页码：1251 / 1256

页数：6

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