Screening of grapes and wine for azoxystrobin, kresoxim-methyl and trifloxystrobin fungicides by HPLC with diode array detection

被引：56

作者：

Abreu, SD ^{[1
]}

Correia, M ^{[1
]}

Herbert, P ^{[1
]}

Santos, L ^{[1
]}

Alves, A ^{[1
]}

机构：

[1] Univ Porto, Fac Engn, LEPAE, DEQ, P-4200465 Oporto, Portugal

来源：

FOOD ADDITIVES AND CONTAMINANTS PART A-CHEMISTRY ANALYSIS CONTROL EXPOSURE & RISK ASSESSMENT | 2005年 / 22卷 / 06期

关键词：

QoI-fungicides; grapes; wines; method validation; HPLC; GC/MS;

D O I：

10.1080/02652030500137918

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The Quinone outside Inhibitors (QoI) are one of the most important and recent fungicide groups used in viticulture and also allowed by Integrated Pest Management. Azoxystrobin, kresoxim-methyl and trifloxystrobin are the main active ingredients for treating downy and powdery mildews that can be present in grapes and wines. In this paper, a method is reported for the analysis of these three QoI-fungicides in grapes and wine. After liquid-liquid extraction and a clean-up on commercial silica cartridges, analysis was by isocratic HPLC with diode array detection (DAD) with a run time of 13 min. Confirmation was by solid-phase micro-extraction (SPME), followed by GC/MS determination. The main validation parameters for the three compounds in grapes and wine were a limit of detection up to 0.073 mg kg(-1), a precision not exceeding 10.0 % and an average recovery of 93 % +/- 38.

引用

页码：549 / 556

页数：8

共 16 条

[1]

[Anonymous], 2000, GUID QUANT UNC AN ME

[2] The strobilurin fungicides [J].

Bartlett, DW ;

Clough, JM ;

Godwin, JR ;

Hall, AA ;

Hamer, M ;

Parr-Dobrzanski, B .

PEST MANAGEMENT SCIENCE, 2002, 58 (07) :649-662

[3]

Cabras P, 1998, J AOAC INT, V81, P1185

[4] Method validation for strobilurin fungicides in cereals and fruit [J].

Christensen, HB ;

Granby, K .

FOOD ADDITIVES AND CONTAMINANTS, 2001, 18 (10) :866-874

[5]

CORREIA M, 2003, THESIS U PORTO, P214

[6]

DUNNE B, 2002, P NAT TILL C

[7]

Giza I, 2003, ACTA CHROMATOGR, V13, P226

[8]

HERBERT P, 2005, IN PRESS INT J ENV A

[9]

*ISO, 2000, 170252000 ISO

[10] Determination of pyrimethanil and kresoxim-methyl in green groceries by headspace solid-phase microextraction and gas chromatography-mass spectrometry [J].

Navalón, A ;

Prieto, A ;

Araujo, L ;

Vílchez, JL .

JOURNAL OF CHROMATOGRAPHY A, 2002, 975 (02) :355-360

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