Tetrahydrophthalic anhydride and imide: Remarkably efficient partners in photochemical [2+2] cycloaddition reactions with alkenols and alkynols

被引：14

作者：

BookerMilburn, KI

Cowell, JK

Sharpe, A

Jimenez, FD

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000249

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Intermolecular photochemical [2 + 2] cycloaddition of a variety of alken- and alkyn-3-ols with 3,4,5,6-tetrahydrophthalic anhydride (THPA) and the related imide 4 gave the corresponding cyclobutanes and cyclobutenes in high yield, after relatively short irradiation times, with stereoselectivities as high as 10:1 for the cyclobutane examples.

引用

页码：249 / 251

页数：3

共 4 条

[1]

BOOKERMILBURN KI, 1995, SYNLETT, P735

[2] MODEL STUDIES TOWARDS THE TOTAL SYNTHESIS OF ASTERISCANOLIDE [J].