Probing the bimetallic RhCo3 cluster preserved on SiO2 after thermal treatment under O-2 by hydroformylation

被引：5

作者：

Huang, L

Xu, Y

机构：

[1] State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 116023 Dalian

来源：

CATALYSIS LETTERS | 1996年 / 40卷 / 3-4期

关键词：

silica-supported RhCo3(CO)(12); oxygen treatment; hydroformylation;

D O I：

10.1007/BF00815283

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

RhCo3(CO)(12)/SiO2, after decarbonylation under atmospheric O-2 at 623 K, exhibits excellent catalytic performances in atmospheric ethylene hydroformylation at 423 K, which is consistent with the corresponding catalysis by the bimetallic cluster catalyst RhCo3/SiO2.

引用

页码：203 / 206

页数：4

共 26 条

[1] PREPARATION OF SOME SUPPORTED METALLIC CATALYSTS FROM METALLIC CLUSTER CARBONYLS [J].

ANDERSON, JR ;

ELMES, PS ;

HOWE, RF ;

MAINWARING, DE .

JOURNAL OF CATALYSIS, 1977, 50 (03) :508-518

[2] SYNTHESIS GAS CONVERSION OVER SUPPORTED RHODIUM AND RHODIUM-IRON CATALYSTS [J].

BHASIN, MM ;

BARTLEY, WJ ;

ELLGEN, PC ;

WILSON, TP .

JOURNAL OF CATALYSIS, 1978, 54 (02) :120-128

[3] SURFACE ORGANOMETALLIC CHEMISTRY ON METALS .1. HYDROGEN AND OXYGEN INTERACTION WITH SILICA-SUPPORTED AND ALUMINA-SUPPORTED RHODIUM [J].

CANDY, JP ;

ELMANSOUR, A ;

FERRETTI, OA ;

MABILON, G ;

BOURNONVILLE, JP ;

BASSET, JM ;

MARTINO, G .

JOURNAL OF CATALYSIS, 1988, 112 (01) :201-209

[4]

CISITSYN AS, 1990, J MOL CATAL, V63, P201

[5] PREPARATION OF SODIUM COBALT TETRACARBONYL [J].

EDGELL, WF ;

LYFORD, J .

INORGANIC CHEMISTRY, 1970, 9 (08) :1932-&

[6] BIMETALLIC PROMOTION OF ALCOHOL PRODUCTION IN CO HYDROGENATION AND OLEFIN HYDROFORMYLATION ON RHFE, PTFE, PDFE, AND IRFE CLUSTER-DERIVED CATALYSTS [J].

FUKUOKA, A ;

KIMURA, T ;

KOSUGI, N ;

KURODA, H ;

MINAI, Y ;

SAKAI, Y ;

TOMINAGA, T ;

ICHIKAWA, M .

JOURNAL OF CATALYSIS, 1990, 126 (02) :434-450

[7] ENHANCEMENT OF OLEFIN HYDROFORMYLATION RELATED TO SUPPORTED BIMETALLIC RH-CO CLUSTERS [J].

HUANG, L ;

XU, YD ;

PIAO, GJ ;

LIU, AM ;

ZHANG, WT .

CATALYSIS LETTERS, 1994, 23 (1-2) :87-95

[8]

HUANG L, IN PRESS J MOL CATAL

[9]

ICHIKAWA M, 1988, POLYHEDRON, V127, P2351

[10] CRITERIA FOR IDENTIFYING TRANSITION-METAL CLUSTER-CATALYZED REACTIONS [J].

LAINE, RM .

JOURNAL OF MOLECULAR CATALYSIS, 1982, 14 (02) :137-169

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