Synthesis of benzo(or furo)[5,6]azepino[2,1-a]isoindolone derivatives:: π-cyclisations of N-acyliminium ions.

被引：39

作者：

Daïch, A

Marchalin, S

Pigeon, P

Decroix, B

机构：

[1] Univ Havre, Fac Sci & Tech, Chim Lab, F-76058 Le Havre, France

[2] Slovak Univ Technol Bratislava, Dept Organ Chem, Bratislava 81237, Slovakia

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 50期

关键词：

Grignard reagents; olefins; azepines; furans;

D O I：

10.1016/S0040-4039(98)02075-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Benzo(or furo)[5,6]azepino[2,1-a]isoindolone and derivatives were obtained easily in one-pot via N-acyliminium ions by treatment of 2-(2-methoxycarbonylbenzyl(or fur-3-yl))phthalimide with alkylmagnesium iodide followed by an acidic hydrolysis. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9187 / 9190

页数：4

共 17 条

[1]

CAPRON B, 1975, B SOC CHIM FR II-CH, P2575

[2] ON THE SYNTHESIS AND REACTIVITY OF 4,10-DIHYDROBENZO[B]THIENO[2,3-E]THIEPIN-10-ACETIC ACID AND 5,10-DIHYDROBENZO[E]THIENO[3,2-B]THIEPIN-10-ACETIC ACID [J].