Universality of ionic criticality: Size- and charge-asymmetric electrolytes

被引:30
作者
Kim, YC
Fisher, ME [1 ]
Panagiotopoulos, AZ
机构
[1] Univ Maryland, Inst Phys Sci & Technol, College Pk, MD 20742 USA
[2] Princeton Univ, Dept Chem Engn, Princeton, NJ 08544 USA
关键词
D O I
10.1103/PhysRevLett.95.195703
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Grand-canonical simulations designed to resolve critical universality classes are reported for z1 hard-core electrolyte models with diameter ratios lambda=a(+)/a(-)less than or similar to 6. For z=1 Ising-type behavior prevails. Unbiased estimates of T-c(lambda) are within 1% of previous (biased) estimates but the critical densities are similar to 5% lower. Ising character is also established for the 21 and 31 equisized models, along with critical amplitudes and improved T-c estimates. For z=3, however, strong finite-size effects reduce the confidence level although classical and O(n >= 3) criticality are excluded.
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页数:4
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共 28 条
  • [1] Ionic criticality: An exactly soluble model
    Aqua, JN
    Fisher, ME
    [J]. PHYSICAL REVIEW LETTERS, 2004, 92 (13) : 135702 - 1
  • [2] Criticality in charge-asymmetric hard-sphere ionic fluids
    Aqua, JN
    Banerjee, S
    Fisher, ME
    [J]. PHYSICAL REVIEW E, 2005, 72 (04):
  • [3] SCALING FIELDS AND UNIVERSALITY OF THE LIQUID-GAS CRITICAL-POINT
    BRUCE, AD
    WILDING, NB
    [J]. PHYSICAL REVIEW LETTERS, 1992, 68 (02) : 193 - 196
  • [4] Critical parameters of unrestricted primitive model electrolytes with charge asymmetries up to 10:1
    Cheong, DW
    Panagiotopoulos, AZ
    [J]. JOURNAL OF CHEMICAL PHYSICS, 2003, 119 (16) : 8526 - 8536
  • [5] How multivalency controls ionic criticality
    Fisher, ME
    Aqua, JN
    Banerjee, S
    [J]. PHYSICAL REVIEW LETTERS, 2005, 95 (13)
  • [6] The shape of the van der Waals loop and universal critical amplitude ratios
    Fisher, ME
    Zinn, S
    [J]. JOURNAL OF PHYSICS A-MATHEMATICAL AND GENERAL, 1998, 31 (37): : L629 - L635
  • [7] FISHER ME, 2005, PHYS REV LETT, V92, P3003
  • [8] Yang-Yang anomalies and coexistence diameters: Simulation of asymmetric fluids
    Kim, YC
    [J]. PHYSICAL REVIEW E, 2005, 71 (05):
  • [9] Discretization dependence of criticality in model fluids: A hard-core electrolyte
    Kim, YC
    Fisher, ME
    [J]. PHYSICAL REVIEW LETTERS, 2004, 92 (18) : 185703 - 1
  • [10] Asymmetric fluid criticality. II. Finite-size scaling for simulations
    Kim, YC
    Fisher, ME
    [J]. PHYSICAL REVIEW E, 2003, 68 (04): : 415061 - 415062