Uranium determination at ppb levels by X-ray fluorescence after its preconcentration on polyurethane foam

被引：42

作者：

Carvalho, MS ^{[1
]}

Domingues, MDF ^{[1
]}

Mantovano, JL ^{[1
]}

Quintino, E ^{[1
]}

机构：

[1] CNEN, Inst Engn Nucl, BR-21945590 Rio De Janeiro, Brazil

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 1998年 / 53卷 / 14期

关键词：

preconcentration; uranium; polyurethane foam; XRF;

D O I：

10.1016/S0584-8547(98)00225-0

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A sensitive method based on the preconcentration of uranium on powdered polyurethane foam (PUF) has been developed to determinate this element in water samples by X-ray florescence. Uranium at ppb levels was sorbed as the salicylate complex on powdered PUF at pH 4.0. The resulting PUF was filtered through a filter paper and used for X-ray fluorescence measurements. For 50 mu g/l of uranium the coefficient of variation for five measurements is 5% and the detection limit is 5.5 mu g/l. The interference level of various ions and ligands was studied and optimum conditions were developed to determine uranium in reference materials, waste water, mine drainage, and sea water. (C) 1998 Published by Elsevier Science B.V.

引用

页码：1945 / 1949

页数：5

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