Carbon nanostructures produced by chlorinating aluminium carbide

被引:78
作者
Leis, J
Perkson, A
Arulepp, M
Käärik, M
Svensson, G
机构
[1] Inst Phys, Lab Mol Engn, EE-51014 Tartu, Estonia
[2] Univ Tartu, Dept Chem, EE-51014 Tartu, Estonia
[3] Tartu Technol Ltd, EE-51014 Tartu, Estonia
[4] Stockholm Univ, Dept Struct Chem, S-10691 Stockholm, Sweden
关键词
carbon/carbon composites; transmission electron microscopy; X-ray diffraction; adsorption; microstructure;
D O I
10.1016/S0008-6223(01)00020-3
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A number of carbon samples with different nanostructures such as: amorphous, nanoparticles and turbostratic, were synthesised through the reaction between aluminium carbide and gaseous chlorine at fixed temperatures between 300 and 900 degreesC. The synthesised carbon samples were characterised using high-resolution transmission electron microscopy and X-ray powder diffraction techniques, as well as low temperature nitrogen sorption measurements. The carbon produced at T=300 degreesC was amorphous with a surface area of similar to 1400 m(2) g(-1). At 700 degreesC, a large amount of carbon nanoparticles and with a lower surface area similar to 710 m(2) g(-1) was obtained. At 900 degreesC, mainly a turbostratic carbon with a surface area of similar to 680 m(2) g(-1) was produced. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:2043 / 2048
页数:6
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