CuO-CeO2 mixed oxide catalysts for the selective oxidation of carbon monoxide in excess hydrogen

被引:246
作者
Avgouropoulos, G
Ioannides, T
Matralis, HK
Batista, J
Hocevar, S
机构
[1] Fdn Res & Technol Hellas, Inst Chem Engn & High Temp Chem Proc, GR-26500 Patras, Greece
[2] Univ Patras, Dept Chem, Chem Phys Sect, GR-26500 Patras, Greece
[3] Natl Inst Chem, Lab Catalysis & Chem React Engn, SI-1001 Ljubljana, Slovenia
关键词
carbon monoxide oxidation; selective oxidation; excess hydrogen; copper; ceria;
D O I
10.1023/A:1009013029842
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series of mixed oxide CuO-CeO2 catalysts were prepared by coprecipitation and tested for the selective oxidation of carbon monoxide in the presence of excess hydrogen. These catalysts were found to be very active and exceptionally selective for this reaction and exhibited a good resistance towards CO2 and H2O. The catalytic performance of these non-noble metal containing catalysts is compared with that of other selective CO oxidation catalysts reported in literature.
引用
收藏
页码:33 / 40
页数:8
相关论文
共 34 条
[1]   HYDROGEN-PRODUCTION BY THE CATALYTIC STEAM REFORMING OF METHANOL .2. KINETICS OF METHANOL DECOMPOSITION USING GIRDLER G66B CATALYST [J].
AMPHLETT, JC ;
EVANS, MJ ;
MANN, RF ;
WEIR, RD .
CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1985, 63 (04) :605-611
[2]  
Appleby A.J., 1989, FUEL CELL HDB
[3]  
BELLOWS RJ, 1997, ELECTROCHEMICAL SOC, V9713, P1
[4]  
BONACCI JC, 1980, Patent No. 4238468
[5]   PURIFYING HYDROGEN BY ... SELECTIVE OXIDATION OF CARBON MONOXIDE [J].
BROWN, ML ;
GREEN, AW ;
COHN, G ;
ANDERSEN, HC .
INDUSTRIAL AND ENGINEERING CHEMISTRY, 1960, 52 (10) :841-844
[6]  
COHN JGE, 1965, Patent No. 3216783
[7]  
DAIMLERBENZ AG, 1996, NECAR, V2
[8]  
ENYO M, 1999, P 3 INT S EL ADV IND, P255
[9]   A NEW APPROACH TO THE PROBLEM OF CARBON-MONOXIDE POISONING IN FUEL-CELLS OPERATING AT LOW-TEMPERATURES [J].
GOTTESFELD, S ;
PAFFORD, J .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1988, 135 (10) :2651-2652
[10]   Impact of catalysis on clean energy in road transportation [J].
Gray, PG ;
Frost, JC .
ENERGY & FUELS, 1998, 12 (06) :1121-1129