Detection of a novel intermediate in the addition of thiols to osmium carbonyl clusters

被引：15

作者：

Kiriakidou, K

Plutino, MR

Prestopino, F

Monari, M

Johansson, M

Elding, LI

Valls, E

Gobetto, R

Aime, S

Nordlander, E

机构：

[1] Univ Lund, Ctr Chem, S-22100 Lund, Sweden

[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40124 Bologna, Italy

[3] Univ Turin, Dipartimento Chim IFM, I-10125 Turin, Italy

来源：

CHEMICAL COMMUNICATIONS | 1998年 / 24期

关键词：

D O I：

10.1039/a807222a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Spectroscopic studies of the reaction of [Os-3(CO)(11)MeCN)] with para-thiocresol to form [Os-3(mu-H)(CO)(10)(mu-SC6H4Me-p)] indicate that the reaction proceeds via a two-step consecutive process involving the intermediate [Os-3(CO)(11)-(MeC6H4SH-p)], in which there is an agostic Os-H-S interaction.

引用

页码：2721 / 2722

页数：2

共 7 条

[1] STEREOCHEMICAL NONRIGIDITY IN (MU(2)-H)(H)OS3(CO)(11) - EVIDENCE FOR THE OCCURRENCE OF A RACEMIZATION PROCESS AT LOW-TEMPERATURE [J].