Composition of soil organic matter and its water-soluble fraction under young vegetation on drift sand, central Netherlands

Podzols tend to form on drift sands in The Netherlands given sufficient time. Differences in organic matter (OM) composition relate to vegetation succession on drift sand that evolves eventually into a micropodzol. We examined the relation between the water-soluble organic matter (WSOM) and the total OM composition in the Ah horizons of the first vegetation stages, under grass (Corynephorus canescens), moss (Polytrichum piliferum), heather (Calluna vulgaris) and pine (Pinus sylvestris), as determined by pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) and analysis of polysaccharides after acid hydrolysis. Polysaccharides dominate the OM in the Ah horizons under grass and moss. Lignin and aliphatic compounds are minor compounds in these profiles, but are mon important under heather and pine. The Py-GC traces of the WSOM under grass and moss contain abundant products derived from polysaccharides. The water-soluble fraction is enriched in phenolic and aliphatic compounds in comparison with their contents in pyrolysates of the total OM. In the WSOM fractions under heather and pine, phenols dominate the pyrolysates, whereas lignin-derived methoxyphenols are rare. Remarkably large amounts of alkenes and alkanes are present in the pyrolysates of these water-soluble fractions, most probably derived from aliphatic biopolymers. Their presence in water might be explained through the formation of colloids, which are stabilized by micelle-like arrangements.