Heteropoly complexes containing titanium .2. Synthesis and characterization of titanotungstocobaltates

被引：17

作者：

Chen, YG

Liu, JF

机构：

[1] Department of Chemistry, Northeast Normal University

来源：

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1997年 / 27卷 / 02期

关键词：

D O I：

10.1080/00945719708000149

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New complexes, M(6)H(2)[(CoW11TiO40)-W-II]. xH(2)O (M = K, x = 12; M = (CH3)(4)N, x = 4), [(CH3)(4)N]H-5(2)[(CoW11TiO40)-W-II]. 6H(2)O and [(CH3)(4)N]H-7[(CoW11)-W-II(TiO2)O-39]. 4H(2)O, have been synthesized and characterized by elemental analysis, IR, UV-Vis and ESR spectroscopy and X-ray photoelectronic spectroscopy. The results show that the three anions have Keggin structure. Their redox property was also examined.

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页码：239 / 249

页数：11

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