Microstructural characterization of lithiated graphite

被引：75

作者：

Song, XY ^{[1
]}

Kinoshita, K ^{[1
]}

Tran, TD ^{[1
]}

机构：

[1] LAWRENCE LIVERMORE NATL LAB,DEPT CHEM & MAT SCI,LIVERMORE,CA 94550

来源：

JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 1996年 / 143卷 / 06期

关键词：

D O I：

10.1149/1.1836896

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The microstructures of lithiated graphite were studied using high-resolution transmission electron microscopy (HRTEM) and x-ray diffraction (XRD). HRTEM shows lattice images of the (001) layers of LiC6 with layer spacing of 3.70 Angstrom, consistent with XRD. The morphology and distribution of the LiC6 and LiC12 phases were investigated by dark field image and selected-area electron diffraction in TEM. The results indicate that LiC6 and LiC12 phases can coexist in the lithiated graphite particle.

引用

页码：L120 / L123

页数：4

共 16 条

[1] THE CORRELATION BETWEEN THE SURFACE-CHEMISTRY AND THE PERFORMANCE OF LI-CARBON INTERCALATION ANODES FOR RECHARGEABLE ROCKING-CHAIR TYPE BATTERIES [J].

AURBACH, D ;

EINELI, Y ;

CHUSID, O ;

CARMELI, Y ;

BABAI, M ;

YAMIN, H .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1994, 141 (03) :603-611

[2]

AURBACH D, 1995, CARBON, V142, P1746

[3] SYNTHESIS AND ELECTRICAL-RESISTIVITY OF LITHIUM-PYROGRAPHITE INTERCALATION COMPOUNDS (STAGE-I, STAGE-II AND STAGE-III) [J].

BILLAUD, D ;

MCRAE, E ;

HEROLD, A .

MATERIALS RESEARCH BULLETIN, 1979, 14 (07) :857-864

[4]

DAHN JR, 1994, NEW MAT DEV PERSPECT, P1

[5] STUDIES OF LITHIUM INTERCALATION INTO CARBONS USING NONAQUEOUS ELECTROCHEMICAL-CELLS [J].

FONG, R ;

VONSACKEN, U ;

DAHN, JR .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1990, 137 (07) :2009-2013

[6] INTERCALATION OF LITHIUM INTO GRAPHITE AND OTHER CARBONS [J].

GUERARD, D ;

HEROLD, A .

CARBON, 1975, 13 (04) :337-345

[7] INTERCALATE ORDERING IN 1ST STAGE GRAPHITE-LITHIUM [J].

KAMBE, N ;

DRESSELHAUS, MS ;

DRESSELHAUS, G ;

BASU, S ;

MCGHIE, AR ;

FISCHER, JE .

MATERIALS SCIENCE AND ENGINEERING, 1979, 40 (01) :1-4

[8]

KINOSHITA K, 1995, 10 INT C SOL STAT IO

[9]

OH WC, 1995, 22 BIENN C CARB SAN

[10] FORMATION OF LITHIUM-GRAPHITE INTERCALATION COMPOUNDS IN NONAQUEOUS ELECTROLYTES AND THEIR APPLICATION AS A NEGATIVE ELECTRODE FOR A LITHIUM ION (SHUTTLECOCK) CELL [J].

OHZUKU, T ;

IWAKOSHI, Y ;

SAWAI, K .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1993, 140 (09) :2490-2498

← 1 2 →