A helical supramolecular polymer formed by host-guest interactions

被引：11

作者：

Miyauchi, M ^{[1
]}

Harada, A ^{[1
]}

机构：

[1] Osaka Univ, Grad Sch Sci, Dept Macromol Sci, Toyonaka, Osaka 5600043, Japan

来源：

CHEMISTRY LETTERS | 2005年 / 34卷 / 01期

关键词：

D O I：

10.1246/cl.2005.104

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

3-[4-(tert-Boc-amino)cinnamoylamino]-alpha-cyclodextrin (3-4-(')BocCiNH-alpha-CD) has been found to form a supramolecular polymer in an aqueous solution. The supramolecular polymer was found to take a helical structure. This is the first example of the formation of a helical supramolecular polymer formed by host-guest interactions.

引用

页码：104 / 105

页数：2

共 15 条

[1] Polycaps: Reversibly formed polymeric capsules [J].

Castellano, RK ;

Rudkevich, DM ;

Rebek, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 1997, 94 (14) :7132-7137

[2]

Corbin PS, 2000, SUPRAMOLECULAR POLYMERS, P147

[3] Supramolecular polymers formed by cinnamoyl cyclodextrins [J].

Harada, A ;

Miyauchi, M ;

Hoshino, T .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (22) :3519-3523

[4] Cyclodextrin-based molecular machines [J].

Harada, A .

ACCOUNTS OF CHEMICAL RESEARCH, 2001, 34 (06) :456-464

[5] Supramolecular polymers formed by modified cyclodextrins [J].

Harada, A ;

Kawaguchi, Y ;

Hoshino, T .

JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2001, 41 (1-4) :115-121

[6] Helical self-assembled polymers from cooperative stacking of hydrogen-bonded pairs [J].

Hirschberg, JHKK ;

Brunsveld, L ;

Ramzi, A ;

Vekemans, JAJM ;

Sijbesma, RP ;

Meijer, EW .

NATURE, 2000, 407 (6801) :167-170

[7] Daisy chain necklace: Tri[2]rotaxane containing cyclodextrins [J].

Hoshino, T ;

Miyauchi, M ;

Kawaguchi, Y ;

Yamaguchi, H ;

Harada, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (40) :9876-9877

[8]

Kaneda T, 2001, CHEM LETT, P1264

[9] INDUCED CIRCULAR-DICHROISM SPECTRUM OF ALPHA-CYCLODEXTRIN COMPLEX WITH HEPTYLVIOLOGEN [J].

KODAKA, M ;

FUKAYA, T .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1989, 62 (04) :1154-1157

[10]

Lehn J.-M., 1995, Supramolecular Chemistry: Concepts and Prospectives

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