Effect of temperature in a closed unstirred Belousov-Zhabotinsky system

被引:34
作者
Masia, M
Marchettini, N
Zambrano, V
Rustici, M
机构
[1] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
[2] Univ Siena, Dipartimento Sci & Tecnol Chim & Biosistemi, I-53100 Siena, Italy
关键词
D O I
10.1016/S0009-2614(01)00474-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Complex periodic and aperiodic behaviours are reported in an unstirred Belousov-Zhabotinsky oscillatory reaction performed at temperatures varying between 0 degreesC and 8 degreesC. A route to chaos following a Ruelle-Takens-Newhouse (RTN) scenario is identified. Thus, temperature effects on the coupling between chemical kinetics, diffusion and convection, seem to be responsible for the observed RTN scenario. In this Letter we demonstrate that the temperature is a bifurcation parameter for the sequence period-1 --> quasiperiodicity --> chaos. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:285 / 291
页数:7
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