Structural investigations into the deactivation pathway of the CO2 reduction electrocatalyst Re(bpy)(CO)3Cl

被引：140

作者：

Benson, Eric E. ^{[1
]}

Kubiak, Clifford P. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 59期

关键词：

RE-RE; COMPLEXES; CONVERSION; CARBONYLS; CRYSTAL; LIGANDS; OTF(-); IR;

D O I：

10.1039/c2cc32617e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report a series of complexes synthesized from the chemical reduction of the fac-tricarbonyl complex Re(bpy)(CO)(3)Cl. Synthesis and characterization of [Re(bpy)(CO)(3)](2), [Re(bpy)(CO)(3)](2)(-), and Re(bpy)(CO)(3)(-) are presented. The Re(bpy)(CO)(3)(-) anion has long been postulated as the active species that reacts with carbon dioxide in the electrochemical reduction of CO2.

引用

页码：7374 / 7376

页数：3

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