Mechanisms of tribochemical film formation: stability of tribo- and thermally-generated ZDDP films

被引：99

作者：

Bancroft, G. M. ^{[1
]}

Kasrai, M. ^{[1
]}

Fuller, M. ^{[1
]}

Yin, Z. ^{[1
]}

Fyfe, K. ^{[2
]}

Tan, Kim H. ^{[3
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

[2] Sarnia Res Ctr, Imperial Oil Prod Div, Sarnia, ON N7T 7M1, Canada

[3] Univ Wisconsin, Canadian Synchrotron Radiat Facil, Stoughton, WI 53589 USA

来源：

TRIBOLOGY LETTERS | 1997年 / 3卷 / 01期

基金：

美国国家科学基金会;

关键词：

antiwear; ZDDP; X-ray absorption; P L-edge XANES;

D O I：

10.1023/A:1019179610589

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Phosphorus L-edge and sulphur L-edge X-ray absorption near-edge structure (XANES) spectroscopy has been used to characterize the chemical nature of tribochemical and thermo-oxidatively generated films from a sec-ZDDP antiwear agent. The chemical stability of the films has been investigated by rubbing the films in base oil without ZDDP. The P L-edge XANES spectra have shown that the thermal film and in particular the tribo-films are very stable after rubbing in the base oil for a long period of time. The wear scar measurements indicate that best results are given if the coupon and pin is coated with a tribo-film and then rubbed in oil containing ZDDP.

引用

页码：47 / 51

页数：5

共 8 条

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