Self-organizing surface-initiated polymerization of perylenediimides on indium tin oxides

被引：22

作者：

Charbonnaz, Pierre ^{[1
]}

Sakai, Naomi ^{[1
]}

Matile, Stefan ^{[1
]}

机构：

[1] Univ Geneva, Sch Chem & Biochem, Geneva, Switzerland

来源：

CHEMICAL SCIENCE | 2012年 / 3卷 / 05期

基金：

欧洲研究理事会;

关键词：

DOUBLE-CHANNEL PHOTOSYSTEMS; CHARGE SEPARATION; BISIMIDE DYES; ARCHITECTURES; PHOTOVOLTAICS; ASSEMBLIES; MOLECULE; SYSTEMS; CELLS;

D O I：

10.1039/c2sc01047j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this study, we demonstrate, for the first time, that SOSIP, self-organizing surface-initiated polymerization, a method introduced for facile access to complex surface architectures, is compatible with perylenediimides (PDIs), i.e., established chromophores with very important properties. Highly ordered face-to-face p-stacks are shown to coincide with a more than 100-fold increase of the activity of PDI photosystems, and with significant fill factors. This breakthrough with electron-transporting PDI stacks promises access to powerful combinations with hole-transporting channels.

引用

页码：1492 / 1496

页数：5

共 37 条

[1] Harnessing supramolecular interactions in organic solid-state devices: Current status and future potential [J].

Bassani, Dario M. ;

Jonusauskaite, Laura ;

Lavie-Cambot, Aurelie ;

McClenaghan, Nathan D. ;

Pozzo, Jean-Luc ;

Ray, Debdas ;

Vives, Guillaume .

COORDINATION CHEMISTRY REVIEWS, 2010, 254 (19-20) :2429-2445

[2] Supramolecular n/p-heterojunction photosystems with oriented multicolored antiparallel redox gradients (OMARG-SHJs']Js) [J].

Bhosale, Rajesh ;

Misek, Jiri ;

Sakai, Naomi ;

Matile, Stefan .

CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) :138-149

[3] Photoproduction of proton gradients with π-stacked fluorophore scaffolds in lipid bilayers [J].

Bhosale, Sheshanath ;

Sisson, Adam L. ;

Talukdar, Pinaki ;

Fuerstenberg, Alexandre ;

Banerji, Natalie ;

Vauthey, Eric ;

Bollot, Guillaume ;

Mareda, Jiri ;

Roger, Cornelia ;

Wuerthner, Frank ;

Sakai, Naomi ;

Matile, Stefan .

SCIENCE, 2006, 313 (5783) :84-86

[4] Supramolecular construction of vesicles based on core-substituted naphthalene diimide appended with triethyleneglycol motifs [J].

Bhosale, Sheshanath V. ;

Jani, Chintan H. ;

Lalander, Cecilia H. ;

Langford, Steven J. ;

Nerush, Igor ;

Shapter, Joseph G. ;

Villamaina, Diego ;

Vauthey, Eric .

CHEMICAL COMMUNICATIONS, 2011, 47 (29) :8226-8228

[5] Monodisperse Co-oligomer Approach toward Nanostructured Films with Alternating Donor-Acceptor Lamellae [J].

Bu, Laju ;

Guo, Xiaoyang ;

Yu, Bo ;

Qu, Yao ;

Xie, Zhiyuan ;

Yan, Donghang ;

Geng, Yanhou ;

Wang, Fosong .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (37) :13242-13243

[6] Photoluminescence and conductivity of self-assembled π-π stacks of perylene bisimide dyes [J].

Chen, Zhijian ;

Stepanenko, Vladimir ;

Dehm, Volker ;

Prins, Paulette ;

Siebbeles, Laurens D. A. ;

Seibt, Joachim ;

Marquetand, Philipp ;

Engel, Volker ;

Wuerthner, Frank .

CHEMISTRY-A EUROPEAN JOURNAL, 2007, 13 (02) :436-449

[7] Dicyanovinyl-Substituted Oligothiophenes: Structure-Property Relationships and Application in Vacuum-Processed Small-Molecule Organic Solar Cells [J].

Fitzner, Roland ;

Reinold, Egon ;

Mishra, Amaresh ;

Mena-Osteritz, Elena ;

Ziehlke, Hannah ;

Koerner, Christian ;

Leo, Karl ;

Riede, Moritz ;

Weil, Matthias ;

Tsaryova, Olga ;

Weiss, Andre ;

Uhrich, Christian ;

Pfeiffer, Martin ;

Baeuerle, Peter .

ADVANCED FUNCTIONAL MATERIALS, 2011, 21 (05) :897-910

[8] Improved Performance of Perylene-Based Photovoltaic Cells Using Polyisocyanopeptide Arrays [J].

Foster, Sam ;

Finlayson, Chris E. ;

Keivanidis, Panagiotis E. ;

Huang, Ya-Shih ;

Hwang, Inchan ;

Friend, Richard H. ;

Otten, Matthiis B. J. ;

Lu, Li-Ping ;

Schwartz, Erik ;

Nolte, Roeland J. M. ;

Rowan, Alan E. .

MACROMOLECULES, 2009, 42 (06) :2023-2030

[9] Excited-state symmetry breaking in cofacial and linear dimers of a green perylenediimide chlorophyll analogue leading to ultrafast charge separation [J].

Giaimo, JM ;

Gusev, AV ;

Wasielewski, MR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (29) :8530-8531

[10] Biomimetic assemblies of carbon nanostructures for photochemical energy conversion [J].

Guldi, DM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (23) :11432-11441

← 1 2 3 4 →