Functionalization vs. β-elimination in alkane activation:: a key role for 16-electron ML5 intermediates

被引：13

作者：

Eisenstein, O

Crabtree, RH

机构：

[1] Univ Montpellier 2, Lab Struct & Dynam Syst Mol & Solides, CNRS, UMR 5636, F-34095 Montpellier, France

[2] Yale Univ, Dept Chem, New Haven, CT 06520 USA

来源：

NEW JOURNAL OF CHEMISTRY | 2001年 / 25卷 / 05期

关键词：

D O I：

10.1039/b101336j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structural preferences in the intermediate ML5 d(6) alkyls are proposed to help determine the reactivity difference between Shilov systems, which convert R-H to R-X via reductive elimination, and alkane dehydrogenation catalysis, where R-H is converted to the alkene, via beta -elimination of an R-M intermediate.

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页码：665 / 666

页数：2

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