Radical-water complexes in Earth's atmosphere

被引:177
作者
Aloisio, S
Francisco, JS [1 ]
机构
[1] Purdue Univ, Dept Chem, W Lafayette, IN 47907 USA
[2] Purdue Univ, Dept Earth & Atmospher Sci, W Lafayette, IN 47907 USA
关键词
D O I
10.1021/ar000097u
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the atmosphere, many chemical processes are controlled by open-shell radical species. While these species are present in relatively small number densities, they initiate many of the cycles that control the chemistry of the atmosphere. The purpose of this Account is to examine recent studies of radical-water complexes that are composed of atmospherically important species. We hope this Account will provide a report on the status of this topical field, while encouraging new research directions.
引用
收藏
页码:825 / 830
页数:6
相关论文
共 82 条
[1]   Complete active space self-consistent field and multireference configuration interaction studies of the differences between the low-lying excited states of HO2 and HO2-H2O [J].
Aloisio, S ;
Li, YM ;
Francisco, JS .
JOURNAL OF CHEMICAL PHYSICS, 1999, 110 (18) :9017-9019
[2]   A density functional study of H2O-OClO, (H2O)2-OClO and H2O-ClOO complexes [J].
Aloisio, S ;
Francisco, JS .
CHEMICAL PHYSICS, 2000, 254 (01) :1-9
[3]   Existence of a hydroperoxy and water (HO2•H2O) radical complex [J].
Aloisio, S ;
Francisco, JS .
JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (11) :1899-1902
[4]   A density functional study of the H2O-HOCO complex [J].
Aloisio, S ;
Francisco, JS .
JOURNAL OF PHYSICAL CHEMISTRY A, 2000, 104 (02) :404-407
[5]   DFT and G2 calculations on the NO2-H2O molecular complex [J].
Ball, DW .
CHEMICAL PHYSICS LETTERS, 1999, 312 (2-4) :306-310
[6]   RATE CONSTANTS FOR THE REACTION OH + CO AS FUNCTIONS OF TEMPERATURE AND WATER CONCENTRATION [J].
BENO, MF ;
JONAH, CD ;
MULAC, WA .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1985, 17 (10) :1091-1101
[7]   MEASUREMENT OF THE PERPENDICULAR ROTATION-TUNNELING SPECTRUM OF THE WATER DIMER BY TUNABLE FAR INFRARED-LASER SPECTROSCOPY IN A PLANAR SUPERSONIC JET [J].
BUSAROW, KL ;
COHEN, RC ;
BLAKE, GA ;
LAUGHLIN, KB ;
LEE, YT ;
SAYKALLY, RJ .
JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (08) :3937-3943
[8]   VANDERWAALS MOLECULES - POSSIBLE ROLES IN THE ATMOSPHERE [J].
CALO, JM ;
NARCISI, RS .
GEOPHYSICAL RESEARCH LETTERS, 1980, 7 (05) :289-292
[9]   CALCULATION OF EQUILIBRIUM MOLE FRACTIONS OF POLAR-POLAR, NONPOLAR-POLAR, AND ION DIMERS [J].
CALO, JM ;
BROWN, JH .
JOURNAL OF CHEMICAL PHYSICS, 1974, 61 (10) :3931-3941
[10]   Density functional studies of the formation of nitrous acid from the reaction of nitrogen dioxide and water vapor [J].
Chou, A ;
Li, ZR ;
Tao, FM .
JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (39) :7848-7855