Controlling Contact Electrification with Photochromic Polymers

被引:40
作者
Friedle, Simone [1 ]
Thomas, Samuel W., III [1 ]
机构
[1] Tufts Univ, Dept Chem, Medford, MA 02155 USA
基金
美国国家科学基金会;
关键词
contact electrification; electrostatics; photochromism; polymers; spiropyran; IONIC ELECTRETS; SURFACES; CRYSTALLIZATION; INSULATORS; SEPARATION; SWITCHES; CHARGE;
D O I
10.1002/anie.201003985
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Charge switching: Control of contact electrification was achieved using a combination of photoreactive polymers and light. Upon UV irradiation, polymers substituted with photochromic spiropyrans reversibly switch their rate, and depending on chemical structure, their sign of charging by contact electrification (see picture). Consistent with empirical predictions, these photochromic polymers tended to charge positively upon irradiation with UV light. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:7968 / 7971
页数:4
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