Improvement of the Zirconia shell in nanostructured titania core-shell working electrodes for dye-sensitized solar cells

被引:19
作者
Menzies, D
Dai, Q [1 ]
Cheng, YB
Simon, GP
Spiccia, L
机构
[1] Monash Univ, Sch Chem, Melbourne, Vic 3800, Australia
[2] Monash Univ, Sch Phys & Mat Engn, Melbourne, Vic 3800, Australia
基金
澳大利亚研究理事会;
关键词
dye-sensitized solar cell; solar energy materials; sol-gel preparation; nanomaterials;
D O I
10.1016/j.matlet.2005.02.048
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Dye-sensitized solar cells (DSSCs) were constructed using nanostructured core-shell working electrodes produced by a sol-gel method. The precursor chemistry was studied by comparing zirconium butoxide and zirconium isopropoxide. Additionally, the concentrations in polar solvents were altered and used on two different titania nanostructures. The electrodes were characterized by photoelectrochemical measurements (PECM). The best efficiencies were recorded for the working electrodes modified with 0.05 M zirconium butoxide in n-butanol at 2.29% from 1.36% (uncoated TiO2) for P25 films and 2.06% from 1.38% (uncoated TiO2) for anatase films under a light intensity of 0.1 Sun. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1893 / 1896
页数:4
相关论文
共 13 条
[1]  
Barbe CJ, 1997, J AM CERAM SOC, V80, P3157, DOI 10.1111/j.1151-2916.1997.tb03245.x
[2]   TiO2-coated nanoporous SnO2 electrodes for dye-sensitized solar cells [J].
Chappel, S ;
Chen, SG ;
Zaban, A .
LANGMUIR, 2002, 18 (08) :3336-3342
[3]   Preparation of Nb2O5 coated TiO2 nanoporous electrodes and their application in dye-sensitized solar cells [J].
Chen, SG ;
Chappel, S ;
Diamant, Y ;
Zaban, A .
CHEMISTRY OF MATERIALS, 2001, 13 (12) :4629-4634
[4]   Core-shell nanoporous electrode for dye sensitized solar cells:: the effect of the SrTiO3 shell on the electronic properties of the TiO2 core [J].
Diamant, Y ;
Chen, SG ;
Melamed, O ;
Zaban, A .
JOURNAL OF PHYSICAL CHEMISTRY B, 2003, 107 (09) :1977-1981
[5]   Interfacial recombination processes in dye-sensitized solar cells and methods to passivate the interfaces [J].
Gregg, BA ;
Pichot, F ;
Ferrere, S ;
Fields, CL .
JOURNAL OF PHYSICAL CHEMISTRY B, 2001, 105 (07) :1422-1429
[6]   Charge recombination in dye-sensitized nanocrystalline TiO2 solar cells [J].
Huang, SY ;
Schlichthorl, G ;
Nozik, AJ ;
Gratzel, M ;
Frank, AJ .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (14) :2576-2582
[7]   Dye-sensitized core-shell nanocrystals:: Improved efficiency of mesoporous tin oxide electrodes coated with a thin layer of an insulating oxide [J].
Kay, A ;
Grätzel, M .
CHEMISTRY OF MATERIALS, 2002, 14 (07) :2930-2935
[8]  
MENZIES DB, 2003, ISES2003 GOT SWED
[9]   A LOW-COST, HIGH-EFFICIENCY SOLAR-CELL BASED ON DYE-SENSITIZED COLLOIDAL TIO2 FILMS [J].
OREGAN, B ;
GRATZEL, M .
NATURE, 1991, 353 (6346) :737-740
[10]   Control of charge recombination dynamics in dye sensitized solar cells by the use of conformally deposited metal oxide blocking layers [J].
Palomares, E ;
Clifford, JN ;
Haque, SA ;
Lutz, T ;
Durrant, JR .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (02) :475-482