Fabrication and magnetic investigation of Y or Gd containing CoFe2O4 nanocrystalline films

被引:27
作者
Yan, CH [1 ]
Cheng, FX [1 ]
Peng, ZY [1 ]
Xu, ZG [1 ]
Liao, CS [1 ]
机构
[1] Peking Univ, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat chem & Applicat, Beijing 100871, Peoples R China
关键词
D O I
10.1063/1.368834
中图分类号
O59 [应用物理学];
学科分类号
摘要
The exertion for carrying out the substitution of Fe3+ ion in CoFe2O4 spinel by Y3+ and Gd3+ ions has been put forth in the present article. Y or Gd containing CoFe2O4 nanocrystalline films with average particles size of 65 nm were synthesized by sol-gel method, and then the magnetic properties of the products were investigated at room temperature. To improve the crystallization of Gd-doped cobalt spinels, we buffered them on about a 20-nm-thick CoFe2O4 thin film. However, the analysis on the results for both x-ray diffraction and magnetic measurement showed that it is difficult to perform the doping of Y3+ ions inside cobalt spinel ferrite. The proper doping amount of magnetic Gd3+ ion can enlarge saturation magnetization (M-s ) and coercive force (H-c)of resultant nanocrystalline films, whereas the doping of Y only reduces them. (C) 1998 American Institute of Physics. [S0021-8979(98)06022-8].
引用
收藏
页码:5703 / 5708
页数:6
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