Nickel(II) complexes of bis(2-diphenylphosphinophenyl)amide

被引:133
作者
Liang, LC [1 ]
Lin, JM
Hung, CH
机构
[1] Natl Sun Yat Sen Univ, Dept Chem, Kaohsiung 80424, Taiwan
[2] Natl Sun Yat Sen Univ, Ctr Nanosci & Nanotechnol, Kaohsiung 80424, Taiwan
[3] Natl Changhua Univ Educ, Dept Chem, Changhua 50058, Taiwan
关键词
D O I
10.1021/om030237e
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of nickel(II) alkyl and aryl complexes supported by the bis(2-diphenylphosphinophenyl)amide ligand, [PNP](-), have been prepared, including those in which the alkyl contains P-hydrogen atoms. The stability of these compounds toward P-elimination is attributed to the rigidity and robustness of the new tridentate amido diphosphine ligand.
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页码:3007 / 3009
页数:3
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