Investigations of solvent-solute interactions in room temperature ionic liquids using solvatochromic dyes

被引：399

作者：

Muldoon, MJ ^{[1
]}

Gordon, CM ^{[1
]}

Dunkin, IR ^{[1
]}

机构：

[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2 | 2001年 / 04期

关键词：

D O I：

10.1039/b101449h

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Different measures of polarity and nucleophilicity of a range of ionic liquids have been investigated using two solvatochromic dyes; the polarity appears to be largely cation controlled, while the donor strength is entirely anion dependent.

引用

页码：433 / 435

页数：3

共 22 条

[1] How polar are room-temperature ionic liquids? [J].

Aki, SNVK ;

Brennecke, JF ;

Samanta, A .

CHEMICAL COMMUNICATIONS, 2001, (05) :413-414

[2] Hydrophobic, highly conductive ambient-temperature molten salts [J].

Bonhote, P ;

Dias, AP ;

Papageorgiou, N ;

Kalyanasundaram, K ;

Gratzel, M .

INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178

[3]

Carmichael AJ, 2000, J PHYS ORG CHEM, V13, P591, DOI 10.1002/1099-1395(200010)13:10<591::AID-POC305>3.0.CO

[4]

2-2

[5]

Chauvin Y, 1995, ANGEW CHEM INT EDIT, V34, P2698

[6]

Chauvin Y., 1995, ANGEW CHEM, V107, P2941

[7] STUDIES ON MIXED CHELATES .1. MIXED COPPER(II) CHELATES WITH N,N,N',N'-TETRAMETHYLETHYLENEDIAMINE AND A BIDENTATE LIGAND [J].

FUKUDA, Y ;

SONE, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1972, 45 (02) :465-+

[8] Weak intermolecular interactions in sulfonamide salts: Structure of 1-ethyl-2-methyl-3 benzyl imidazolium bis[(trifluoromethyl)sulfonyl]amide [J].

Golding, JJ ;

Macfarlane, DR ;

Spiccia, L ;

Forsyth, M ;

Skelton, BW ;

White, AH .

CHEMICAL COMMUNICATIONS, 1998, (15) :1593-1594

[9] Room temperature ionic liquids of alkylimidazolium cations and fluoroanions [J].

Hagiwara, R ;

Ito, Y .

JOURNAL OF FLUORINE CHEMISTRY, 2000, 105 (02) :221-227

[10] HYDROGEN-BOND ACCEPTOR ABILITIES OF TETRACHLOROMETALATE(II) COMPLEXES IN IONIC LIQUIDS [J].

HITCHCOCK, PB ;

SEDDON, KR ;

WELTON, T .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (17) :2639-2643

← 1 2 3 →