A general method to fluorous ponytail-substituted aromatics

被引：40

作者：

Chen, WP ^{[1
]}

Xu, LJ ^{[1
]}

Xiao, JL ^{[1
]}

机构：

[1] Univ Liverpool, Dept Chem, Leverhulme Ctr Innovat Catalysis, Liverpool L69 7ZD, Merseyside, England

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 25期

基金：

英国工程与自然科学研究理事会;

关键词：

fluorinated aromatics; Heck reaction; fluorous ponytails; palladium catalysts;

D O I：

10.1016/S0040-4039(01)00714-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Palladium-catalyzed olefination of aryl halides led to a variety of fluorous ponytail-substituted, functionalized aryl compounds with good to excellent yields. The same chemistry was also applied to the synthesis of binaphathols bearing fluorinated ponytails. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：4275 / 4278

页数：4

共 22 条

[1] Barthel-Rosa LP, 1999, COORDIN CHEM REV, V190, P587
[2] Palladium-catalyzed cross-coupling of organozinc bromides with aryl iodides in perfluorinated solvents
Betzemeier, B
Knochel, P
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (23) : 2623 - 2624
[3] Phosphorus(III) ligands with fluorous ponytails
Bhattacharyya, P
Gudmunsen, D
Hope, EG
Kemmitt, RDW
Paige, DR
Stuart, AM
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1997, (24): : 3609 - 3612
[4] Palladium-catalyzed synthesis of aqueous, fluorous, and supercritical CO2-soluble phosphines
Chen, WP
Xu, LJ
Xiao, JL
[J]. ORGANIC LETTERS, 2000, 2 (17) : 2675 - 2677
[5] Novel and efficient synthesis of perfluoroalkylated arylphosphines
Chen, WP
Xiao, JL
[J]. TETRAHEDRON LETTERS, 2000, 41 (19) : 3697 - 3700
[6] Darses S, 2001, EUR J ORG CHEM, V2001, P1121
[7] Fluorous phase separation techniques in catalysis
de Wolf, E
van Koten, G
Deelman, BJ
[J]. CHEMICAL SOCIETY REVIEWS, 1999, 28 (01) : 37 - 41
[8] Fish RH, 1999, CHEM-EUR J, V5, P1677, DOI 10.1002/(SICI)1521-3765(19990604)5:6<1677::AID-CHEM1677>3.3.CO
[9] 2-O
[10] FUCHIKAMI T, 1981, SYNTHESIS-STUTTGART, P365

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