Two-photon microstructure-polymerization initiated by a coumarin derivative/iodonium salt system

被引:49
作者
Li, CD
Luo, L
Wang, SF
Huang, WT
Gong, QH [1 ]
Yang, YY
Feng, SJ
机构
[1] Peking Univ, State Key Lab Mesoscop Phys, Beijing 100871, Peoples R China
[2] Peking Univ, Dept Phys, Beijing 100871, Peoples R China
[3] Acad Sinica, Inst Photog Chem, Beijing 100101, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1016/S0009-2614(01)00416-X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Two-photon polymerization initiated by a bimolecular initiating system composed of 7-diethylamino-3-(2 ' -benzimidazolyl)coumarin and diphenyliodonium hexafluorophosphate was investigated. The photosensitizer has been proven to possess large two-photon absorption cross-section for 800 nm femtosecond laser. The sensitizer/coinitiator system has high photosensitivity for the photopolymerization of methyl methacrylate. This photopolymer system has been demonstrated for fabricating three-dimensional microstructure. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:444 / 448
页数:5
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