Interfacial Photoreduction of Supercritical CO2 by an Aqueous Catalyst

被引：58

作者：

Mendez, Manuel A. ^{[1
]}

Voyame, Patrick ^{[1
]}

Girault, Hubert H. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Lab Electrochim Phys & Analyt, Stn 6, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 32期

关键词：

adsorption; carbon dioxide; cyclam; photochemistry; supercritical fluids; CARBON-DIOXIDE; PHOTOCHEMICAL REDUCTION; LIQUID/LIQUID INTERFACES; PHOTOCATALYTIC REDUCTION; NICKEL(II) CYCLAM; OXYGEN REDUCTION; VISIBLE-LIGHT; WATER; COMPLEXES; COBALT;

D O I：

10.1002/anie.201100828

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Not just a solvent anymore: CO2 reduction under supercritical conditions was achieved in a biphasic water-supercritical CO2 system using an aqueous soluble catalyst (see picture). The introduction of such an interface provides a suitable reaction medium where adsorption, CO2 binding, and protonation of intermediates are intimately linked. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：7391 / 7394

页数：4

共 42 条

[1] Boundary tension by pendant drops
Andreas, JM
Hauser, EA
Tucker, WB
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1938, 42 (08) : 1001 - 1019
[2] Cobalt porphyrin catalyzed reduction of CO2.: Radiation chemical, photochemical, and electrochemical studies
Behar, D
Dhanasekaran, T
Neta, P
Hosten, CM
Ejeh, D
Hambright, P
Fujita, E
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1998, 102 (17) : 2870 - 2877
[3] NICKEL(II) CYCLAM - AN EXTREMELY SELECTIVE ELECTROCATALYST FOR REDUCTION OF CO2 IN WATER
BELEY, M
COLLIN, JP
RUPPERT, R
SAUVAGE, JP
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1984, (19) : 1315 - 1316
[4] ELECTROCATALYTIC REDUCTION OF CO2 BY NI CYCLAM2+ IN WATER - STUDY OF THE FACTORS AFFECTING THE EFFICIENCY AND THE SELECTIVITY OF THE PROCESS
BELEY, M
COLLIN, JP
RUPPERT, R
SAUVAGE, JP
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (24) : 7461 - 7467
[5] COMPLEXES OF NICKEL(2) WITH A CYCLIC TETRADENTATE SECONDARY AMINE
BOSNICH, B
TOBE, ML
WEBB, GA
[J]. INORGANIC CHEMISTRY, 1965, 4 (08) : 1109 - &
[6] Using a One-Electron Shuttle for the Multielectron Reduction of CO2 to Methanol: Kinetic, Mechanistic, and Structural Insights
Cole, Emily Barton
Lakkaraju, Prasad S.
Rampulla, David M.
Morris, Amanda J.
Abelev, Esta
Bocarsly, Andrew B.
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (33) : 11539 - 11551
[7] ELECTROCATALYTIC PROPERTIES OF NI(CYCLAM)2+ AND NI2(BISCYCLAM)4+ WITH RESPECT TO CO2 AND H2O REDUCTION
COLLIN, JP
JOUAITI, A
SAUVAGE, JP
[J]. INORGANIC CHEMISTRY, 1988, 27 (11) : 1986 - 1990
[8] PHOTOCHEMICAL REDUCTION OF CARBON-DIOXIDE USING NICKEL TETRAAZAMACROCYCLES
CRAIG, CA
SPREER, LO
OTVOS, JW
CALVIN, M
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1990, 94 (20) : 7957 - 7960
[9] EXCITED-STATE PHOTOCHEMISTRY IN THE TRIS(2,2'-BIPYRIDINE)RUTHENIUM(II)-SULFITE SYSTEM
CREUTZ, C
SUTIN, N
BRUNSCHWIG, BS
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (05) : 1297 - 1298
[10] p-terphenyl-sensitized photoreduction of CO2 with cobalt and iron porphyrins.: Interaction between CO and reduced metalloporphyrins
Dhanasekaran, T
Grodkowski, J
Neta, P
Hambright, P
Fujita, E
[J]. JOURNAL OF PHYSICAL CHEMISTRY A, 1999, 103 (38) : 7742 - 7748

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