EXAFS study of electrolytic nanosolution confined in interstitial nanospaces of single-wall carbon nanohorn colloids

被引：10

作者：

Ohkubo, T. ^{[1
,2
]}

Hattori, Y. ^{[3
]}

Kanoh, H. ^{[1
,4
]}

Konishi, T. ^{[1
,4
]}

Sakai, H. ^{[2
]}

Abe, M. ^{[2
]}

Kasuya, D.

Yudasaka, M. ^{[5
]}

Iijima, S. ^{[5
,6
,7
]}

Fujikawa, T. ^{[1
,4
]}

Kaneko, K. ^{[1
,4
]}

机构：

[1] Chiba Univ, Fac Sci, Dept Chem, Chiba 2638522, Japan

[2] Tokyo Univ Sci, Fac Sci & Technol, Chiba 2788510, Japan

[3] Inst Res & Innovat, Chiba 2770861, Japan

[4] Chiba Univ, Ctr Frontier Elect & Photon, Chiba 2638522, Japan

[5] Japan Sci & Technol Corp, Tsukuba, Ibaraki 3058501, Japan

[6] Meijo Univ, Fac Sci & Technol, Nagoya, Aichi 4688502, Japan

[7] NEC Corp Ltd, Tsukuba, Ibaraki 3058501, Japan

来源：

PHYSICA SCRIPTA | 2005年 / T115卷

关键词：

D O I：

10.1238/Physica.Topical.115a00685

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

The structure of RbBr aqueous solution confined in the interstitial nanospaces of single-wall carbon nanohorn (SWNH) assemblies was elucidated by using extended X-ray absorption fine structure (EXAFS) technique. The decrease of hydration number around a Rb ion is clearly observed. The EXAFS analysis indicates that the highly distorted and dehydrated structure around ions of aqueous solution confined in the nanospace (nanosolution: NSN) to form quasi one-dimensional structure in the interstitial nanospaces of SWNH assemblies. This unique hydration structures formed in nanospaces of SWNH is quite different from that not only of the bulk aqueous solution, but also confined in the slit-shaped nanospaces of activated carbon fiber (ACF).

引用

页码：685 / 687

页数：3

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