Electrospinning of poly(vinylidene fluoride)/dimethylformamide solutions with carbon nanotubes

被引:120
作者
Seoul, C [1 ]
Kim, YT [1 ]
Baek, CK [1 ]
机构
[1] Inha Univ, Dept Text Engn, Inchon 402751, South Korea
关键词
electrospinning; carbon nanotubes; poly(vinylidene fluoride); dimethylformamide; percolation threshold; electrical conductivity; viscosity; surface tension; fibers; mat;
D O I
10.1002/polb.10511
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
For conductive carbon nanotube (CN)/polymer composite fibers to be obtained, CNs were incorporated into poly(vinylidene fluoride) (PVDF) in dimethylformamide (DMF) solutions and electrospun to form CN/PVDF fiber mats. The thinnest fiber was 70 nm thick. The percolation threshold for the insulator-to-conductor transition was 0.003 wt % CN for CN/PVDF/DMF solutions, 0.015 wt % CN for CN/PVDF spin-coated films, and 0.04 wt % CN for CN/PVDF electrospun fiber mats. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码:1572 / 1577
页数:6
相关论文
共 15 条
[1]  
[Anonymous], 2018, INTRO PERCOLATION TH
[2]  
BRANDRUP J, 1989, POLYM HDB, P415
[3]   Electrospinning of polyurethane fibers [J].
Demir, MM ;
Yilgor, I ;
Yilgor, E ;
Erman, B .
POLYMER, 2002, 43 (11) :3303-3309
[4]   Preparation and characterization of nanoscaled poly(vinyl alcohol) fibers via electrospinning [J].
Ding, B ;
Kim, HY ;
Lee, SC ;
Lee, DR ;
Choi, KJ .
FIBERS AND POLYMERS, 2002, 3 (02) :73-79
[5]   Beaded nanofibers formed during electrospinning [J].
Fong, H ;
Chun, I ;
Reneker, DH .
POLYMER, 1999, 40 (16) :4585-4592
[6]   Aligned single-wall carbon nanotubes in composites by melt processing methods [J].
Haggenmueller, R ;
Gommans, HH ;
Rinzler, AG ;
Fischer, JE ;
Winey, KI .
CHEMICAL PHYSICS LETTERS, 2000, 330 (3-4) :219-225
[7]  
KYMAKIS E, 2001, J SYN MET, V9108, P1
[8]  
Lau KT, 2002, COMPOS PART B-ENG, V33, P263
[9]   Electrostatic fabrication of ultrafine conducting fibers: polyaniline/polyethylene oxide blends [J].
Norris, ID ;
Shaker, MM ;
Ko, FK ;
MacDiarmid, AG .
SYNTHETIC METALS, 2000, 114 (02) :109-114
[10]  
SEOUL C, 1994, J KOREAN FIBER SOC, V31, P217