5,10,15,20-tetrakis(N-protected-imidazol-2-yl)porphyrins.

被引：38

作者：

Milgrom, LR

Dempsey, PJF

Yahioglu, G

机构：

[1] Department of Chemistry, Brunel University, Uxbridge

来源：

TETRAHEDRON | 1996年 / 52卷 / 29期

关键词：

D O I：

10.1016/0040-4020(96)00520-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

it is shown that examples of the title porphyrins can be prepared from suitably N-protected imidazole-2-carboxaldehydes and pyrrole in refluxing propionic acid: subsequent deprotection, affords a synthetic route to 5,10,15,20-tetrakis(substituted-imidazol-2-yl)porphyrins (TIPs). Copyright (C) 1996 Elsevier Science Ltd

引用

页码：9877 / 9890

页数：14

共 28 条

[1] A SIMPLIFIED SYNTHESIS FOR MESO-TETRAPHENYLPORPHIN [J].

ADLER, AD ;

LONGO, FR ;

FINARELLI, JD ;

GOLDMACH.J ;

ASSOUR, J ;

KORSAKOF.L .

JOURNAL OF ORGANIC CHEMISTRY, 1967, 32 (02) :476-+

[2]

[Anonymous], 1987, INTRO SYNTHETIC ELEC

[3]

ANWER MK, 1978, SYNTHESIS-STUTTGART, P75

[4]

Ashwell GJ., 1992, Molecular Electronics

[5] NOVEL METHODS FOR DEMETALATING TETRAPYRROLIC METALLO-MACROCYCLES [J].

BATTERSBY, AR ;

JONES, K ;

SNOW, RJ .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1983, 22 (09) :734-735

[6]

BRUIX M, 1992, J CHEM RES-S, P370

[7] PICKET-FENCE PORPHYRINS - SYNTHETIC MODELS FOR OXYGEN BINDING HEMOPROTEINS [J].

COLLMAN, JP ;

GAGNE, RR ;

REED, CA ;

HALBERT, TR ;

LANG, G ;

ROBINSON, WT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1427-1439

[8]

COTTON FA, 1980, ADV INORG CHEM, P787

[9] STERIC EFFECTS ON ATROPISOMERISM IN TETRAARYLPORPHYRINS [J].

CROSSLEY, MJ ;

FIELD, LD ;

FORSTER, AJ ;

HARDING, MM ;

STERNHELL, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (02) :341-348

[10]

CUNNINGHAM J, 1964, TETRAHEDRON LETT, P1191

← 1 2 3 →