Graphite epoxide

被引：60

作者：

Chattopadhyay, Jayanta

Mukherjee, Arnab

Hamilton, Christopher E.

Kang, JungHo

Chakraborty, Soma

Guo, Wenhua

Kelly, Kevin F.

Barron, Andrew R.

Billups, W. Edward

机构：

[1] Rice Univ, Dept Chem, Houston, TX 77005 USA

[2] Rice Univ, Richard E Smalley Inst Nanoscale Sci & Technol, Houston, TX 77005 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 16期

关键词：

D O I：

10.1021/ja711063f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

w Oxidation of graphite may be carried out by reaction with meta-chloroperoxybenzoic acid to yield graphite epoxide. Scanning tunneling microscopy (STIM) showed that the functionalization occurs at the edges rather than on the basal plane of the graphite. Quantification of the epoxide content is possible through the deepoxidation reaction using MeReO3/PPh3.

引用

页码：5414 / +

页数：3

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