Enhanced two-photon absorption with novel octupolar propeller-shaped fluorophores derived from triphenylamine

被引:251
作者
Porrés, L
Mongin, O
Katan, C
Charlot, M
Pons, T
Mertz, J
Blanchard-Desce, M
机构
[1] Univ Rennes 1, Inst Chim, CNRS, UMR 6510, F-35042 Rennes, France
[2] Ecole Super Phys & Chim Ind Ville Paris, INSERM, CNRS, EPI 00 02,FRE 2500, F-75231 Paris, France
关键词
D O I
10.1021/ol036041s
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Novel octupolar fluorophores derived from the symmetrical functionalization of a triphenylamine core with strong acceptor peripheral groups via phenylene-ethynylene linkers have been synthesized and shown to exhibit high fluorescence quantum yields, very large TPA cross-sections in the red-NIR region, and suitable photostability.
引用
收藏
页码:47 / 50
页数:4
相关论文
共 61 条
[1]   Novel heteroaromatic-based multi-branched dyes with enhanced two-photon absorption activity [J].
Abbotto, A ;
Beverina, L ;
Bozio, R ;
Facchetti, A ;
Ferrante, C ;
Pagani, GA ;
Pedron, D ;
Signorini, R .
CHEMICAL COMMUNICATIONS, 2003, (17) :2144-2145
[2]   Novel heterocycle-based two-photon absorbing dyes [J].
Abbotto, A ;
Beverina, L ;
Bozio, R ;
Facchetti, A ;
Ferrante, C ;
Pagani, GA ;
Pedron, D ;
Signorini, R .
ORGANIC LETTERS, 2002, 4 (09) :1495-1498
[3]  
Abbotto A, 2000, ADV MATER, V12, P1963, DOI 10.1002/1521-4095(200012)12:24<1963::AID-ADMA1963>3.3.CO
[4]  
2-J
[5]   Novel two-photon absorbing dendritic structures [J].
Adronov, A ;
Fréchet, JMJ ;
He, GS ;
Kim, KS ;
Chung, SJ ;
Swiatkiewicz, J ;
Prasad, PN .
CHEMISTRY OF MATERIALS, 2000, 12 (10) :2838-+
[6]   Design of organic molecules with large two-photon absorption cross sections [J].
Albota, M ;
Beljonne, D ;
Brédas, JL ;
Ehrlich, JE ;
Fu, JY ;
Heikal, AA ;
Hess, SE ;
Kogej, T ;
Levin, MD ;
Marder, SR ;
McCord-Maughon, D ;
Perry, JW ;
Röckel, H ;
Rumi, M ;
Subramaniam, C ;
Webb, WW ;
Wu, XL ;
Xu, C .
SCIENCE, 1998, 281 (5383) :1653-1656
[7]   A systematic femtosecond study on the two-photon absorbing D-π-A molecules-π-bridge nitrogen insertion and strength of the donor and acceptor groups [J].
Antonov, L ;
Kamada, K ;
Ohta, K ;
Kamounah, FS .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2003, 5 (06) :1193-1197
[8]   Two-photon photochromism of an organic material for holographic recording [J].
Belfield, KD ;
Liu, Y ;
Negres, RA ;
Fan, M ;
Pan, G ;
Hagan, DJ ;
Hernandez, FE .
CHEMISTRY OF MATERIALS, 2002, 14 (09) :3663-3667
[9]   New two-photon absorbing fluorene derivatives: Synthesis and nonlinear optical characterization [J].
Belfield, KD ;
Hagan, DJ ;
Van Stryland, EW ;
Schafer, KJ ;
Negres, RA .
ORGANIC LETTERS, 1999, 1 (10) :1575-1578
[10]   A new photosensitive polymeric material for WORM optical data storage using multichannel two-photon fluorescence readout [J].
Belfield, KD ;
Schafer, KJ .
CHEMISTRY OF MATERIALS, 2002, 14 (09) :3656-3662