The adsorption of monolayer coatings on iron nanoparticles: Mossbauer spectroscopy and XANES results

被引:32
作者
Kataby, G
Koltypin, Y
Rothe, J
Hormes, J
Felner, I
Cao, X
Gedanken, A [1 ]
机构
[1] Bar Ilan Univ, Dept Chem, IL-52900 Ramat Gan, Israel
[2] Hebrew Univ Jerusalem, Racah Inst Phys, IL-91904 Jerusalem, Israel
[3] Univ Bonn, Inst Phys, D-5300 Bonn, Germany
关键词
amorphous materials; nanostructures; XANES spectroscopy; Mossbauer spectroscopy;
D O I
10.1016/S0040-6090(98)00802-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Recently coatings on amorphous iron and amorphous iron oxide nanoparticles were successfully formed, using the self-assembled technique. The results of the Mossbauer spectroscopy and XANES studies of thiol-coated nanophased amorphous iron are reported in this work. They provide more support in demonstrating the formation of chemical bonds between the amorphous iron and the various surfactants. A trivalent iron atom is detected as bound to the SDS surfactant by both: XANES and Mossbauer spectroscopies. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:41 / 49
页数:9
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