Destruction of chemical warfare agents VX and soman by α-nucleophiles as oxidizing agents

被引：30

作者：

Cassagne, T

Cristau, HJ

Delmas, G

Desgranges, M

Lion, C

Magnaud, G

Torreilles, E

Virieux, D

机构：

[1] ENSCM, Chim Organ Lab, CNRS, UMR 5076, F-34296 Montpellier 5, France

[2] Univ Paris 07, Inst Topol & Dynam Syst, UPRESA 7086, F-75005 Paris, France

[3] Minist Def, Ctr Etud Bouchet, F-91710 Vert Le Petit, France

来源：

HETEROATOM CHEMISTRY | 2001年 / 12卷 / 06期

关键词：

D O I：

10.1002/hc.1074

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of O-ethyl S-(2-diisopropylamino)ethyl methylphosphonothiolate, VX 1, were investigated with five oxidizing agents. In all the cases, the formation of the VX N-oxide 7 was observed prior to the subsequent oxidation and hydrolysis into the nontoxic O-ethyl methylphosphonate 2. Magnesium monoperoxyphthalate (MMPP) is probably one of the most active reagents to achieve the complete detoxification of VX 1. The decontamination using MMPP was also extended with success to soman 13, a G-type agent. (C) 2001 John Wiley & Sons, Inc.

引用

页码：485 / 490

页数：6

共 16 条

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