Solvolytic routes to new nonabismuth hydroxy- and alkoxy-oxo complexes:: synthesis, characterization and solid-state structures of novel nonabismuth polyoxo cations Bi9(μ3-O)8(μ3-OR)65+ (R = H, Et)

被引：37

作者：

Thurston, JH ^{[1
]}

Swenson, DC ^{[1
]}

Messerle, L ^{[1
]}

机构：

[1] Univ Iowa, Dept Chem, Iowa City, IA 52242 USA

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 33期

关键词：

D O I：

10.1039/b504864h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Base hydrolysis of BiO(ClO4) yields ClO4- salts of the novel nonabismuth polyoxo cation Bi-9(mu(3)-O)(8)(mu(3)-OH)(6)(5+) (1); ethanolysis converts 1 to the ethoxide Bi-9(mu(3)-O)(8)(mu(3)-OEt)(6)(5+) (2).

引用

页码：4228 / 4230

页数：3

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