Stable cubic phosphorus-containing radicals

被引：54

作者：

Armstrong, A

Chivers, T ^{[1
]}

Parvez, M

Boeré, RT

机构：

[1] Univ Calgary, Dept Chem, Calgary, AB T2N 1N4, Canada

[2] Univ Lethbridge, Dept Chem & Biochem, Lethbridge, AB T1K 3M4, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 04期

关键词：

cubanes; lithium; main group elements; phosphorus; radicals;

D O I：

10.1002/anie.200353108

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Stable, deep-blue neutral radicals [(Me3SiN) P (μ 3-NtBu)3{μ3-Li(thf)}3X] (X = Br, I) with distorted cubic structures are obtained by the oxidation of [{Li 3[P(NtBu)3(NSiMe3)]}2] with halogens in THF (see picture). The cubes comprise the radical dianion [P(NtBu)3(NSiMe3)].2-. two Li+ ions, and a molecule of LiX. Solvation in very dilute THF solution releases (thf)3LiX and generates the cyclic radical monoanion [(Me 3SiN)(tBuN) P (μ-NtBu)2Li(thf)2] .-.

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页码：502 / 505

页数：4

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