Tweaking copper hydride (CuH) for synthetic gain. A practical, one-pot conversion of dialkyl ketones to reduced trialkylsilyl ether derivatives

被引：51

作者：

Lipshutz, BH ^{[1
]}

Caires, CC ^{[1
]}

Kuipers, P ^{[1
]}

Chrisman, W ^{[1
]}

机构：

[1] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

ORGANIC LETTERS | 2003年 / 5卷 / 17期

关键词：

D O I：

10.1021/ol035164+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Variations in the reagents and stoichiometries used to generate CuH in situ, as well as the nature of the ligands present, have led to a very efficient and inexpensive method for effecting hydrosilylations of dialkyl ketones.

引用

页码：3085 / 3088

页数：4

共 27 条

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